A most brilliant colleague of mine was able to find a quick and easy workaround for this pesky issue.
In this scenario, the users to be CC'd are contained in a multiple person/group field in the list that the workflow is running on, called 'Assigned To Secondary'
To solve the problem:
- set workflow var:SecondaryAssigned to CurrentItem:Assigned To Secondary (formatted as a string)
- if workflow var:SecondaryAssigned is not empty
- set workflow var:SecondaryAssignedAddr to workflow var:SecondaryAssigned (formatted as email address, semicolon delimited)
- send email
- in the CC portion, select workflow var:SecondaryAssignedAddr (formatted as a string)
http://geekswithblogs.net/DinoGrl/archive/2012/04/24/sharepoint-2010-how-to-insert-multiple-persongroup-field-contents-into.aspx